The food and beverage
industry implements stringent guidelines on
the quality of carbon dioxide utilised in products
for human consumption. Organo sulphur compounds
are extremely odourous and can cause tainting
to product. Bottled carbon dioxide (CO
2)
can sometimes contain impurities. The most common
impurities are acetaldehyde, methanol, ethanol,
hydrogen sulphide, carbonyl sulphide and sulphur
dioxide.
Organo sulphur compounds can also be present
in alcoholic beverages such as wine and beer.
The presence can be due to the degradation of
sulphur containing amino acids. The table below
demonstrates the sulphur compounds that can
be present in beer at ppb and ppm levels. The
impurities can produce off-odours or flavours
and as the products age the sulphur species
impurities can modify and impact shelf life
and future value.
In some cases, sulphur compounds add characteristic
tastes and aromas to foods. Through examination
of these compounds at various stages in either
the growth or processing of beverages you can
reveal the keys to improving the final product.
Volatile
sulphur containing compounds found in
beer at ppm to ppb levels. |
Hydrogen
sulphide
Isopropyl mercaptan
Carbonyl sulphide
Methyl ethyl sulphide
Methyl mercaptan
n-propyl mercaptan
|
Ethyl
mercaptan
t-butyl mercaptan
Sulphur dioxide
Sec-butyl mercaptan
Dimethyl sulphide
Diethyl sulphide
|
Dimethyl
disulphide
Isobutyl mercaptan
Carbon dioxide
n-butyl mercaptan
t-amyl mercaptan
|
Speciated sulphur analysis by Gas Chromatography
- Sulphur Chemiluminescence Detector (GC-SCD)
can identify odours, flavours, and delineate
natural versus synthetic flavours or identify
imposters. The SCD allows sulphur compounds
to be measured at extremely low levels in comparison
to other techniques. The SCD also provides selectivity
and is not subject to response quenching from
hydrocarbon matrices. Leeder Consulting can
also offer analysis of volatile organics in
CO2 including benzene.
 |
Quality Assurance and Quality
Control are primary considerations when
undertaking food analysis. Leeder Consulting
is AS/NZS ISO Certified, the laboratory
is NATA Accredited, a Registered Quarantine
Laboratory and “Appointed Analyst”
under the Commonwealth Imported Food Control
Act. |